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2-Hydroxypropyl methacrylate

CAS No.:923-26-2
Product Grade: Industrial Grade
Purity / Assay: ≥97%
Molecular Formula:C₇H₁₂O₃
Molecular Weight:144.17 g/mol
Synonym(s):2-Hydroxypropyl methacrylate, HPMA, 2-Hydroxypropyl 2-methylprop-2-enoate

2-Hydroxypropyl methacrylate (HPMA) is a clear, colorless liquid monomer characterized by its dual functionality, possessing both a polymerizable vinyl group and a reactive hydroxyl group. This unique structure makes it a versatile building block in polymer chemistry, enabling the synthesis of copolymers with tailored chemical and physical properties. It is typically stabilized with inhibitors to ensure shelf life and is compatible with a wide range of organic solvents and water.
In industrial and research settings, HPMA is valued for its ability to introduce hydrophilicity and reactive sites into polymer chains. These sites allow for subsequent cross-linking, which enhances the mechanical strength and chemical resistance of the resulting materials. Its relatively low volatility and high reactivity make it a preferred choice for various polymerization techniques, including solution and emulsion processes.
Handling this monomer requires attention to its reactive nature, particularly its sensitivity to heat and light. It is commonly used as a functional monomer to improve adhesion to substrates and to modify the rheological properties of liquid formulations. Its role as an intermediate is crucial for developing high-performance resins that demand a balance of flexibility, durability, and environmental resistance.

• In the coatings and paints industry, 2-Hydroxypropyl methacrylate is a vital co-monomer for producing thermosetting acrylic resins and automotive finishes. The hydroxyl groups facilitate cross-linking with melamine or isocyanate curing agents, resulting in coatings with high gloss, excellent hardness, and superior resistance to weathering and chemical exposure.

• The monomer is extensively used in the formulation of adhesives and sealants to improve bonding performance on polar substrates. By incorporating HPMA, manufacturers can enhance the adhesion, flexibility, and impact resistance of acrylic-based adhesive systems. It is also a key ingredient in anaerobic adhesives, where its reactive nature ensures rapid curing and high structural integrity.

• In the field of specialty polymers, HPMA is a primary component for manufacturing hydrogels and soft contact lens materials. Its hydrophilic properties contribute to high water content and excellent oxygen permeability in the final polymer matrix. These characteristics are essential for applications requiring biocompatibility and controlled moisture retention in various environmental conditions.

• HPMA-based copolymers serve as effective binders and finishing agents in the textile and paper industries. These polymers improve the surface characteristics of paper products and enhance the dyeability and crease resistance of textile fibers. The presence of hydroxyl groups allows for strong chemical bonding to cellulosic materials, ensuring that the functional treatments remain durable throughout the product’s lifecycle.

200kg/drum, IBC Drum
CAS No.: 923-26-2

Product Name: 2-Hydroxypropyl methacrylate

Purity / Assay:≥97%
Molecular Formula:C₇H₁₂O₃
Molecular Weight:144.17 g/mol
EINECS No.:213-090-3
Synonym(s):2-Hydroxypropyl methacrylate, HPMA, 2-Hydroxypropyl 2-methylprop-2-enoate

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